Beilstein J. Org. Chem.2011,7, 246–253, doi:10.3762/bjoc.7.33
nucleophile is not necessary to form oxazolidinones. The metal is probably bonded to the allylic system from the same face as the nucleophile.
Keywords: bicyclic endoperoxides; biscarbamates; oxazolidinone; Pd-catalyzedallylicreaction; singlet oxygen; Introduction
Palladium-catalyzed carbon–carbon bond
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Graphical Abstract
Scheme 1:
General route to oxazolidinones via a palladium-catalyzed reaction.